Front Cover: Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes (Eur. J. Inorg. Chem. 41/2021)

Front Cover: Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes (Eur. J. Inorg. Chem. 41/2021) ArticleGenre_short.OTHER

Journal

European Journal of Inorganic Chemistry
ISSN: 1434-1948

Output data

Year: 2021, Volume: 2021, Number: 41, Pages: 4238-4238 Pages count : 1 DOI: 10.1002/ejic.202100784

Authors

Kireev Nikolay V. ¹ , Kiryutin Alexey S. ² , Pavlov Alexander A. ¹ , Yurkovskaya Alexandra V. ² , Musina Elvira I. ³ , Karasik Andrey A. ³ , Shubina Elena S. ¹ , Ivanov Konstantin L. ² , Belkova Natalia V. ¹

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences Vavilov Street 28, 119991 Moscow, Russia
2	International Tomography Center Novosibirsk State University Pirogova street 1, Novosibirsk, 630090, Russia
3	A. E. Arbuzov Institute of Organic and Physical Chemistry Kazan Scientific Center Russian Academy of Sciences

The Front Cover shows the reversible H2 heterolytic splitting/H2 production by nickel diazadiphosphacyclooctane complexes [Ni(PR12NR22)2]2+ in which the nickel(II) dihydrogen complex so far remained the undetected intermediate. The use of a particular bait (para-hydrogen) allowed bringing this species to light with the help of the specially equipped submarine (PArtially NEgative Line experiments in NMR). The chosen set of R1, R2 substituents stabilizes nickel(II) hydride products, preventing their irreversible conversion into Ni(0) complexes. The authors thank Ekaterina Gulyaeva for creating the cover design. More information can be found in the Full Paper by K. L. Ivanov, N. V. Belkova and co-workers. https://doi.org/10.1002/ejic.202100489

Kireev N.V. , Kiryutin A.S. , Pavlov A.A. , Yurkovskaya A.V. , Musina E.I. , Karasik A.A. , Shubina E.S. , Ivanov K.L. , Belkova N.V.
Front Cover: Nickel(II) Dihydrogen and Hydride Complexes as the Intermediates of H2 Heterolytic Splitting by Nickel Diazadiphosphacyclooctane Complexes (Eur. J. Inorg. Chem. 41/2021)
European Journal of Inorganic Chemistry. 2021. V.2021. N41. P.4238-4238. DOI: 10.1002/ejic.202100784 OpenAlex

Submitted:	Jun 7, 2021
Accepted:	Aug 4, 2021
Published online:	Sep 12, 2021

OpenAlex:

W3209491626

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