Synthesis, Molecular and Crystal Structures of Polyfluoroaryl-Substituted Aminodiaza- and Aminotriazadamantanes

Synthesis, Molecular and Crystal Structures of Polyfluoroaryl-Substituted Aminodiaza- and Aminotriazadamantanes Full article

Journal

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Output data

Year: 2025, Volume: 66, Number: 2, Pages: 338-345 Pages count : 8 DOI: 10.1134/s0022476625020118

Authors

Kudryavtseva E.N. ¹ , Medved′ko A.V. ¹ , Arutyunyan A.D. ² , Gevorkyan K.A. ² , Galstyan M.V. ² , Gasparyan S.P. ² , Vatsadze S.Z. ¹ , Romanenko G.V. ³ , Korlyukov A.A. ⁴ , Tretyakov E.V. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Scientific Technological Center of Organic and Pharmaceutical Chemistry of the National Academy of Sciences of the Republic of Armenia, Yerevan, Armenia
3	International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
4	Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

4-((5,7-Dimethyl-1,3-diazaadamantan-6-yl)amino)-2,3,5,6-tetrafluorobenzonitrile, 5,7-dimethyl-N-(2,3,5,6-tetrafluoro-4-nitrophenyl)-1,3-diazaadamantane-6-amine, 4-((1,3,5-triaza-adamantan-7-yl)amino)-2,3,5,6-tetrafluorobenzonitrile, and N-(2,3,5,6-tetrafluoro-4-nitrophenyl)-1,3,5-triaza-adamantane-7-amine are prepared by the interaction of 5,7-dimethyl-1,3-diazaadamantane-6-amine or 1,3,5-triazaadamantane-7-amine with the corresponding polyfluorinated aromatic compound (perfluorobenzonitrile or perfluoronitrobenzene). All the compounds are structurally characterized by NMR and IR spectroscopy, high-resolution mass spectrometry, and XRD. The structures of triazaadamantane derivatives, in contrast to substituted diazaadamantanes, contain multiple short F⋯F contacts.

Kudryavtseva E.N. , Medved′ko A.V. , Arutyunyan A.D. , Gevorkyan K.A. , Galstyan M.V. , Gasparyan S.P. , Vatsadze S.Z. , Romanenko G.V. , Korlyukov A.A. , Tretyakov E.V.
Synthesis, Molecular and Crystal Structures of Polyfluoroaryl-Substituted Aminodiaza- and Aminotriazadamantanes
Journal of Structural Chemistry (Журнал структурной химии). 2025. V.66. N2. P.338-345. DOI: 10.1134/s0022476625020118 WOS Scopus

Published online:

Mar 10, 2025

Web of science:	WOS:001441528700016
Scopus:	2-s2.0-105000019998

Пока нет цитирований