Design of a New Class of Mesoionic Compounds Based on Benzodioxolene Derivatives with Annulated 2-Aryl-1,3-dithiolium Moiety

Design of a New Class of Mesoionic Compounds Based on Benzodioxolene Derivatives with Annulated 2-Aryl-1,3-dithiolium Moiety Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632

Output data

Year: 2025, Volume: 95, Number: 7, Pages: 1804-1816 Pages count : 13 DOI: 10.1134/s1070363225602492

Authors

Norkov S.V. ¹ , Makarov S.G. ¹ , Baranov E.V. ¹ , Fukin G.K. ¹ , Romanenko G.V. ² , Kuropatov V.A. ¹

Affiliations

1	G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, Nizhny Novgorod, 603950 Russia
2	International Tomography Center of Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090 Russia

An efficient one-step method for preparation of mesoionic derivatives of sterically hindered benzodioxolenes containing an annulated 2-aryl-1,3-dithiole fragment was developed. The anionic and cationic parts in these species are predominantly localized on the dioxolene site and in the 1,3-dithiole heterocycle, respectively. The nature of the aryl substituent in the 2-position of the 1,3-dithiole cycle determines the spatial structure of the molecule and the features of intermolecular interactions during the formation of packing in the crystalline phase.

Norkov S.V. , Makarov S.G. , Baranov E.V. , Fukin G.K. , Romanenko G.V. , Kuropatov V.A.
Design of a New Class of Mesoionic Compounds Based on Benzodioxolene Derivatives with Annulated 2-Aryl-1,3-dithiolium Moiety
Russian Journal of General Chemistry. 2025. V.95. N7. P.1804-1816. DOI: 10.1134/s1070363225602492 WOS Scopus

Accepted:	May 19, 2025
Published print:	Aug 5, 2025

Web of science:	WOS:001545472400017
Scopus:	2-s2.0-105012591730

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