Biradical with the “non-linear” diacetylene fragment

Biradical with the “non-linear” diacetylene fragment Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285

Output data

Year: 2008, Volume: 57, Number: 2, Pages: 394-399 Pages count : 6 DOI: 10.1007/s11172-008-0060-5

Authors

Tolstikov S.E. ^1,2 , Tretyakov E.V. ^1,2 , Romanenko G.V. ¹ , Stass D.V. ³ , Bogomyakov A.S. ^1,2 , Sagdeev R.Z. ¹ , Ovcharenkoa V.I. ¹

Affiliations

1	International Tomography Center, Siberian Branch of the Russian Academy of Sciences
2	Novosibirsk State University
3	Institute of chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences

The nitronyl nitroxide biradical, 2,2′-[1,1′-(hexa-2,4-diyne-1,6-diyl)bis(1H-pyrazole-4,1-diyl)]bis(4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole 3-oxide 1-oxyl), was synthesized. The structure and magnetic properties of the biradical were studied. In the solid state, this nitroxide contains the nonlinear CS-C≡C-C≡C-CS fragment. The CS-C≡C and C≡C-C≡ angles are 172.4(5) and 171.1(3)°, respectively.

Tolstikov S.E. , Tretyakov E.V. , Romanenko G.V. , Stass D.V. , Bogomyakov A.S. , Sagdeev R.Z. , Ovcharenkoa V.I.
Biradical with the “non-linear” diacetylene fragment
Russian Chemical Bulletin. 2008. V.57. N2. P.394-399. DOI: 10.1007/s11172-008-0060-5 WOS Scopus

Толстиков С.Е. , Третьяков Е.В. , Романенко Г.В. , Стась Д.В. , Богомяков , Сагдеев Р.З. , Овчаренко В.И.
Бирадикал с «нелинейным» диацетиленовым фрагментом
Известия Академии наук. Серия химическая. 2008. №2. С.385-390.

Web of science:	WOS:000263155800023
Scopus:	2-s2.0-59849124123

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