Structure of Mn(II), Co(II), Ni(II), and Cu(II) complexes with triformylmethane

Structure of Mn(II), Co(II), Ni(II), and Cu(II) complexes with triformylmethane Full article

Journal

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Output data

Year: 2013, Volume: 54, Number: 1, Pages: 104-109 Pages count : 6 DOI: 10.1134/s0022476613010149

Authors

Tretyakov E.V. ¹ , Tolstikov S.E. ¹ , Romanenko G.V. ¹ , Bogomyakov A.S. ¹ , Sagdeev R.Z. ^1,2 , Novotortsev V.M. ² , Ovcharenko V.I. ^1,2

Affiliations

1	International Tomography Center, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
2	N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

Previously unknown [ML2(H2O) n ] bischelates, where M is Mn(II), Co(II), Ni(II), or Cu(II) and L is deprotonated triformylmethane, are studied by X-ray diffraction analysis. It is revealed that in the crystals of all compounds there are multiple hydrogen bonds linking bischelate molecules into polymer layers or a single framework. The character of the temperature dependence of the effective magnetic moment [ML2(H2O) n ] indicates the existences of weak intracrystalline exchange interactions between the unpaired electrons of the paramagnetic centers.

Tretyakov E.V. , Tolstikov S.E. , Romanenko G.V. , Bogomyakov A.S. , Sagdeev R.Z. , Novotortsev V.M. , Ovcharenko V.I.
Structure of Mn(II), Co(II), Ni(II), and Cu(II) complexes with triformylmethane
Journal of Structural Chemistry (Журнал структурной химии). 2013. V.54. N1. P.104-109. DOI: 10.1134/s0022476613010149 WOS Scopus

Третьяков Е.В. , Толстиков С.Е. , Романенко Г.В. , Богомяков А.С. , Сагдеев Р.З. , Новоторцев В.М. , Овчаренко В.И.
Структура комплексов Mn(II), Co(II), Ni(II) и Cu(II) с триформилметаном
Journal of Structural Chemistry (Журнал структурной химии). 2013. Т.54. №1. С.111-116.

Published print:

Mar 26, 2013

Web of science:	WOS:000316757800014
Scopus:	2-s2.0-84875667525

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