1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers

1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers Full article

Journal

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Output data

Year: 2020, Volume: 61, Number: 5, Pages: 707-711 Pages count : 5 DOI: 10.1134/s0022476620050054

Tags

4,4′-(triaz-1-ene-1,3-diyl)dipyridine, coordination polymer, hexafluoroacetylacetonate, copper

Authors

Romanenko G.V. ¹ , Tolstikov S.E. ¹ , Fursova E.Yu. ¹ , Ovcharenko V.I. ¹

Affiliations

1	International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

4,4′-(Triaz-1-ene-1,3-diyl)dipyridine (L) and the first transition metal complex with it are synthesized. It is found that the solid phase of isolated solvate [Cu(hfac)2L]·0.5MePh, where hfac is hexafluoroacetylacetonate, consists of polymer chains inside which L acts as a bridge, linking together Cu(hfac)2 moieties by N atoms of pyridine rings. The chains, in turn, are arranged into layers by H bonds. The result shows that L can be a bridging ligand in the synthesis of new coordination polymers.

Romanenko G.V. , Tolstikov S.E. , Fursova E.Y. , Ovcharenko V.I.
1,3-Di(4-Pyridyl)Triazene: A New Ligand for the Synthesis of Coordination Polymers
Journal of Structural Chemistry (Журнал структурной химии). 2020. V.61. N5. P.707-711. DOI: 10.1134/s0022476620050054 WOS Scopus

Романенко Г.В. , Толстиков С.Е. , Фурсова Е.Ю. , Овчаренко В.И.
1,3-Ди(4-пиридил)триазен — новый лиганд для синтеза координационных полимеров
Journal of Structural Chemistry (Журнал структурной химии). 2020. Т.61. №5. С.748-752. DOI: 10.26902/JSC_id55414

Published online:

Aug 8, 2020

Web of science:	WOS:000558500500005
Scopus:	2-s2.0-85089213239

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