In Situ Monitoring of Heterogeneous Catalytic Hydrogenation via 129Xe NMR Spectroscopy and Proton MRI

In Situ Monitoring of Heterogeneous Catalytic Hydrogenation via 129Xe NMR Spectroscopy and Proton MRI Full article

Journal

ACS Catalysis
ISSN: 2155-5435

Output data

Year: 2020, Volume: 10, Number: 2, Pages: 1417-1422 Pages count : 6 DOI: 10.1021/acscatal.9b05000

Authors

Burueva Dudari B. ^1,2 , Pokochueva Ekaterina V. ^1,2 , Wang Xinpei ^3,4 , Filkins Max ^4,5 , Svyatova Alexandra ^1,2 , Rigby Sean P. ⁵ , Wang Chengbo ³ , Pavlovskaya Galina E. ^6,4 , Kovtunov Kirill V. ^1,2 , Meersmann Thomas ^6,4 , Koptyug Igor V. ^1,2

Affiliations

1	International Tomography Center SB RAS, 3A Institutskaya St., 630090 Novosibirsk, Russia
2	Novosibirsk State University, 2 Pirogova St., 630090 Novosibirsk, Russia
3	Faculty of Science and Engineering, University of Nottingham Ningbo China, 199 Taikang East RD, Ningbo 315100, China
4	Sir Peter Mansfield Imaging Centre, University of Nottingham, Nottingham NG7 2RD, United Kingdom
5	Department of Chemical and Environmental Engineering, University of Nottingham, Nottingham NG7 2RD, United Kingdom
6	Division of Respiratory Medicine, School of Medicine, University of Nottingham, Nottingham NG7 2HU, United Kingdom

The ability to use molecular hydrogen, H2, as a buffer gas in spin exchange optical pumping of noble gases enables the production of hydrogen gas containing a low percentile (5%) of hyperpolarized (HP) 129Xe as a tracer for in situ NMR spectroscopy of hydrogenation reactions. It is demonstrated that the xenon chemical shift, observed in the porous space of Pt-containing alumina pellets, can be used to monitor the temperature changes under rapidly progressing, nonsteady-state conditions during start-up of the catalytic reaction. Standard proton MR imaging was successfully applied to provide in situ evaluation of conversion for the catalyst used in this work.

Burueva D.B. , Pokochueva E.V. , Wang X. , Filkins M. , Svyatova A. , Rigby S.P. , Wang C. , Pavlovskaya G.E. , Kovtunov K.V. , Meersmann T. , Koptyug I.V.
In Situ Monitoring of Heterogeneous Catalytic Hydrogenation via 129Xe NMR Spectroscopy and Proton MRI
ACS Catalysis. 2020. V.10. N2. P.1417-1422. DOI: 10.1021/acscatal.9b05000 WOS Scopus

Submitted:	Nov 18, 2019
Published online:	Dec 30, 2019
Published print:	Jan 17, 2020

Web of science:	WOS:000508466700046
Scopus:	2-s2.0-85078653902

DB	Citing
Scopus	12
Web of science	10