Re(i)-nitroxide complexes | Sciact

Re(i)-nitroxide complexes Full article

Journal

RSC Advances
ISSN: 2046-2069

Output data

Year: 2021, Volume: 11, Number: 32, Pages: 19902-19907 Pages count : 6 DOI: 10.1039/d1ra02159a

Tags

cyrhetrenes, nitronyl nitroxide, EPR, CV, XRD, magnetochemistry

Authors

Maryunina Kseniya ¹ , Letyagin Gleb ^1,2 , Bogomyakov Artem ^1,2,3 , Morozov Vitaly ^1,2 , Tumanov Sergey ^1,2 , Veber Sergey ^1,2 , Fedin Matvey ^1,2 , Saverina Evgeniya ³ , Syroeshkin Mikhail ³ , Egorov Mikhail ³ , Romanenko Galina ¹ , Ovcharenko Victor ^1,3

Affiliations

1	International Tomography Center SB RAS, Institutskaya Str. 3a, 630090 Novosibirsk, Russia
2	Novosibirsk State University, Pirogova Str. 1, 630090 Novosibirsk, Russia
3	N. D. Zelinsky Institute of Organic Chemistry RAS, Leninsky Prospect, 47, Moscow, Russia

Spin-labeled cyrhetrenes [(NNCp)Re(CO)3] and [(INCp)Re(CO)3], where NNCp is nitronyl nitroxide 2-(h5-cyclopentadienyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl and INCp is the corresponding imino nitroxide, were synthesized and characterized by EPR, CV, XRD, magnetochemistry and quantum chemistry methods. The correlations between diﬀerent arrangements of paramagnetic centers and the magnetic exchange interactions for three polymorphs of [(NNCp)Re(CO)3] were studied. It was concluded that high kinetic stability of nitroxide-substituted cyrhetrenes is a promising feature of compounds for the creation of multifunctional contrast agents.

Maryunina K. , Letyagin G. , Bogomyakov A. , Morozov V. , Tumanov S. , Veber S. , Fedin M. , Saverina E. , Syroeshkin M. , Egorov M. , Romanenko G. , Ovcharenko V.
Re(i)-nitroxide complexes
RSC Advances. 2021. V.11. N32. P.19902-19907. DOI: 10.1039/d1ra02159a WOS Scopus

Published online:

Jun 2, 2021

Web of science:	WOS:000660243300061
Scopus:	2-s2.0-85107825844

DB	Citing
Scopus	4
Web of science	4