Mononuclear complexes of Mn(II) and Co(II) with ferrocenecarboxylic acid

Mononuclear complexes of Mn(II) and Co(II) with ferrocenecarboxylic acid Full article

Journal

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Output data

Year: 2022, Volume: 63, Number: 10, Pages: 1579-1583 Pages count : 5 DOI: 10.1134/s0022476622100043

Authors

Romanenko G.V. ¹ , Tolstikov S.E. ¹ , Fursova E.Yu. ¹ , Ovcharenko V.I. ¹

Affiliations

1	International Tomography Center, Siberian Branch, Russian Academy of Scienses, Novosibirsk, Russia

Mononuclear coordination complexes of Mn(II) and Co(II) with ferrocenecarboxylic acid (FcCOOH) with the composition (NBu4)2[M(FcCOO)3(H2O)2)](FcCOO) are prepared. The XRD study showed that the distorted octahedral environment of the metal atom is formed by oxygen atoms of two water molecules and three FcCOO– anions in such a way that two anions are monodentate coordinated and one anion is bidentate-cyclic. The fourth anion is H-bonded with coordinated water molecules. Negatively charged {[M(FcCOO)3(H2O)2)](FcCOO)}– fragments, containing a new type of mononuclear transition metal carboxylate complex, are separated by tetrabutylammonium cations.

Romanenko G.V. , Tolstikov S.E. , Fursova E.Y. , Ovcharenko V.I.
Mononuclear complexes of Mn(II) and Co(II) with ferrocenecarboxylic acid
Journal of Structural Chemistry (Журнал структурной химии). 2022. V.63. N10. P.1579-1583. DOI: 10.1134/s0022476622100043 WOS Scopus

Романенко Г.В. , Толстиков С.Е. , Фурсова Е.Ю. , Овчаренко В.И.
Моноядерные комплексы Mn(II) и Co(II) с ферроценкарбоновой кислотой
Journal of Structural Chemistry (Журнал структурной химии). 2022. Т.63. №10. 99181 :1-5. DOI: 10.26902/JSC_id99181

Published online:

Nov 3, 2022

Web of science:	WOS:000878674700004
Scopus:	2-s2.0-85141221977

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