Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation

Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation Full article

Journal

Journal of Molecular Structure
ISSN: 0022-2860

Output data

Year: 2017, Volume: 1130, Pages: 855-859 Pages count : 6 DOI: 10.1016/j.molstruc.2016.10.088

Tags

O-ligands, Diazacrown, Crystal structure, NMR

Authors

Vasilchenko Danila ^1,2 , Tkachev Sergey ¹ , Baidina Iraida ¹ , Romanenko Galina ³ , Korenev Sergey ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Science, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	International Tomography Centre, Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane (DCH2)2+) was used for the efﬁcient isolation of the homoleptic platinum complexes [Pt(NO3)6]2- and [Pt(C2O4)2]2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH22þ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H2O)n(NO3)6-n]n-2 species.

Vasilchenko D. , Tkachev S. , Baidina I. , Romanenko G. , Korenev S.
Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation
Journal of Molecular Structure. 2017. V.1130. P.855-859. DOI: 10.1016/j.molstruc.2016.10.088 WOS Scopus

Published print:

Dec 9, 2016

Web of science:	WOS:000390731800098
Scopus:	2-s2.0-85002948559

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Scopus	8
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