Effect of the solvent on the formation of new oxovanadium(IV) complexes with pentafluorobenzoate anions and 1,10-phenanthroline

Effect of the solvent on the formation of new oxovanadium(IV) complexes with pentafluorobenzoate anions and 1,10-phenanthroline Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693

Output data

Year: 2023, Volume: 544, Article number : 121238, Pages count : 6 DOI: 10.1016/j.ica.2022.121238

Tags

Oxovanadium(IV) complexes, Pentafluorobenzoate, 1,10-phenanthroline, Crystal structure, Magnetic susceptibility, EPR spectroscopy

Authors

Bazhina Evgeniya S. ¹ , Kiskin Mikhail A. ¹ , Babeshkin Konstantin A. ¹ , Efimov Nikolay N. ¹ , Fedin Matvey V. ² , Eremenko Igor L. ¹

Affiliations

1	Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prosp. 31, 119991 Moscow, Russia
2	International Tomography Center of the Siberian Branch of the Russian Academy of Sciences, Institutskaya St. 3a, 630090 Novosibirsk, Russia

Depending on the solvent ratio MeCN: EtOH, the reaction of [VO(H2O)5](otf)2 (otf = O3SCF3) with 1,10-phenanthroline (phen) and lithium pentafluorobenzoate (Li(O2C2C6F5) = Li(pfbz)) affords crystals of heteronuclear compound [Li2(VO)2(µ-pfbz)6(phen)2]·2MeCN (1), mononuclear complex [VO(pfbz)(phen)2](otf) (2) and binuclear complex [(VO)2(μ-OH)(μ-pfbz)2(phen)2](otf)·MeCN·H2O (3). The structures of new compounds 1–3 were determined by X-ray diffraction. According to magnetochemical and EPR spectroscopy data, the paramagnetic VIV centers in structures 1 and 2 are magnetically isolated, and in compound 3, spin–spin antiferromagnetic exchange interactions between vanadium ions are realized (J = –138 cm−1).

Bazhina E.S. , Kiskin M.A. , Babeshkin K.A. , Efimov N.N. , Fedin M.V. , Eremenko I.L.
Effect of the solvent on the formation of new oxovanadium(IV) complexes with pentafluorobenzoate anions and 1,10-phenanthroline
Inorganica Chimica Acta. 2023. V.544. 121238 :1-6. DOI: 10.1016/j.ica.2022.121238 WOS Scopus OpenAlex

Web of science:	WOS:001150331500001
Scopus:	2-s2.0-85139870882
OpenAlex:	W4302009358

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