Crystal-structural study of complex compounds of the acetates and propionates of the rare earth elements with urea and thiourea. Crystal structure of the complex of diaquotria cetatolanthanum with thiourea [La(C2H3O2)3(H2O)2]⋅SC(NH2)2

Crystal-structural study of complex compounds of the acetates and propionates of the rare earth elements with urea and thiourea. Crystal structure of the complex of diaquotria cetatolanthanum with thiourea [La(C2H3O2)3(H2O)2]⋅SC(NH2)2 Full article

Journal

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Output data

Year: 1980, Volume: 21, Number: 3, Pages: 348-351 Pages count : 4 DOI: 10.1007/bf00746857

Authors

Romanenko G.V. ¹ , Podberezskaya N.V. ¹ , Bakakin V.V. ¹ , Sakharova Yu.G. ²

Affiliations

1	Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR.
2	Saratov State University

An X-ray structural study of the complex compound formed by La acetate with thiourea and water [La(C2H302)3(H20)2]. SC(NI-12) 2 has been carried out. The structure is of the chain-isolated unit type. The chains of La ten-apex figures, formed by the oxygen atoms of the acetate groups and the water molecules, are created by the linking of common edges and extend along [100]. The thiourea molecules are situated between them, and interact with the La polyhedron through hydrogen bonds S... H-OH20. The bond lengths in the acetate groups and thiourea have their usual values.

Romanenko G.V. , Podberezskaya N.V. , Bakakin V.V. , Sakharova Y.G.
Crystal-structural study of complex compounds of the acetates and propionates of the rare earth elements with urea and thiourea. Crystal structure of the complex of diaquotria cetatolanthanum with thiourea [La(C2H3O2)3(H2O)2]⋅SC(NH2)2
Journal of Structural Chemistry (Журнал структурной химии). 1980. V.21. N3. P.348-351. DOI: 10.1007/bf00746857 WOS Scopus

Web of science:	WOS:A1980KZ36300018
Scopus:	2-s2.0-34250246255

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