Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum

Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum Full article

Journal

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Output data

Year: 2017, Volume: 58, Pages: 1689–1692 Pages count : 4 DOI: 10.1134/S0022476617080315

Authors

Vasilchenko D.B. ^1,2 , Zadesenets A.V. ^1,2 , Baidina I.A. ¹ , Piryazev D.A. ¹ , Romanenko G.V. ³

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2	Novosibirsk National Research State University, Russia
3	International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Platinum(II) complexes cis-[Pt(NH3)2I2] (1) and trans-[Pt(NH3)2(N3)2] (2) are structurally characterized separately for the first time. The crystallographic data are as follows: for 1, a = 7.0065(6) Å, b = 6.8714(6) Å, c = 7.4106(8) Å, β = 108.432(7)°, space group P21/m, Z = 2, ρcalc = 4.739 g/cm3; for 2, a = 8.1337(5) Å, b = 11.5821(7) Å, c = 6.9705(5) Å, β = 107.256(2)°, space group P21/c, Z = 4, ρcalc = 3.318 g/cm3. Platinum atoms have a square planar environment; the main structure-forming factor is the presence of intermolecular hydrogen bonds forming chain motifs in the structure of 1 and a threedimensional framework in the structure of 2.

Vasilchenko D.B. , Zadesenets A.V. , Baidina I.A. , Piryazev D.A. , Romanenko G.V.
Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum
Journal of Structural Chemistry (Журнал структурной химии). 2017. V.58. P.1689–1692. DOI: 10.1134/S0022476617080315 WOS Scopus

Васильченко Д.Б. , Задесенец А.В. , Байдина И.А. , Пирязев Д.А. , Романенко Г.В.
Кристаллические структуры цис-дииододиамминплатины и транс-диазидодиамминплатины
Journal of Structural Chemistry (Журнал структурной химии). 2017. Т.58. №8. С.1739-1742. DOI: 10.26902/jsc20170831

Web of science:	WOS:000424028500031
Scopus:	2-s2.0-85041577022

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