Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen

Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen Научная публикация

Журнал

Carbon
ISSN: 1873-3891

Вых. Данные

Год: 2023, Том: 201, Страницы: 535-541 Страниц : 7 DOI: 10.1016/j.carbon.2022.09.050

Ключевые слова

Methane conversion,Zeolite-templated carbons, Light hydrocarbons, Mo/ZSM-5,Zeolite topology

Авторы

Liu Yujie ¹ , Osta Elisabet Huertas ¹ , Poryvaev Artem S. ^2,5 , Fedin Matvey V. ^2,5 , Longo Alessandro ³ , Nefedov Alexei ⁴ , Kosinov Nikolay ¹

Организации

1	Laboratory of Inorganic Materials & Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, the Netherlands
2	International Tomography Center SB RAS, 630090, Novosibirsk, Russia
3	European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France and Istituto per lo Studio dei Materiali Nanostrutturati (ISMN)-CNR UOS Palermo, Via Ugo La Malfa, 153, 90146, Palermo, Italy
4	Karlsruher Institut für Technologie (KIT), Institut für Funktionelle Grenzflächen (IFG), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
5	Novosibirsk State University, 630090, Novosibirsk, Russia

Efficient direct valorization of methane to value-added chemicals and materials remains an unsolved challenge for modern chemistry and materials science. In this work, we explored direct non-oxidative conversion of methane to hydrogen, hydrocarbons, and valuable zeolite-templated carbon materials. First, using a set of spectroscopy and microscopy characterization tools, we investigated how the reaction conditions influence the process of carbon formation inside the typical zeolite-based catalyst Mo/ZSM-5. Then, we explored the effect of the zeolite topology on the growth of carbon materials from methane decomposition over Mo/MFI, Mo/MOR, Mo/BEA, and Mo/FAU templates. Finally, we applied the obtained insights to prepare high-quality zeolite-templated carbons directly from methane using Fe/BEA and Fe/FAU templates. Altogether, our results represent a carbon-economic method of methane conversion to COx-free hydrogen gas, a mixture of light aliphatic and aromatic hydrocarbons, and valuable carbon materials

Liu Y. , Osta E.H. , Poryvaev A.S. , Fedin M.V. , Longo A. , Nefedov A. , Kosinov N.
Direct conversion of methane to zeolite-templated carbons, light hydrocarbons, and hydrogen
Carbon. 2023. V.201. P.535-541. DOI: 10.1016/j.carbon.2022.09.050 WOS OpenAlex

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