Spin-Labeled Linker for the Design of Coordination Polymers | Sciact

Spin-Labeled Linker for the Design of Coordination Polymers Научная публикация

Журнал

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Вых. Данные

Год: 2020, Том: 61, Номер: 6, Страницы: 906-913 Страниц : 8 DOI: 10.1134/s0022476620060104

Авторы

Romanenko G.V. ¹ , Fokin S.V. ¹ , Tolstikov S.E. ¹ , Letyagin G.A. ^1,2 , Bogomyakov A.S. ^1,2 , Ovcharenko V.I. ¹

Организации

1	International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

The synthesis of a novel nitronylnitroxyl radical 2-(2,5-di(pyridin-4-yl)phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl (L) and the first Mn(II) complex with it [Mn(NO3)2(L)(H2O)× ×(i-PrOH)] is elaborated and performed. It is found that the complex is formed by polymeric chains in which (NO3)2(H2O)(i-PrOH) fragmentы are linked by L coordinated by N atoms of pyridine rings. The chains are combined into layers by hydrogen bonds between the coordinated water molecules, i-PrOH, and nitrate anions. The layers are joined into a framework by weak C-H⋯O contacts between O atoms of the nitronylnitroxyl fragment and the pyridine C-H group.

Romanenko G.V. , Fokin S.V. , Tolstikov S.E. , Letyagin G.A. , Bogomyakov A.S. , Ovcharenko V.I.
Spin-Labeled Linker for the Design of Coordination Polymers
Journal of Structural Chemistry (Журнал структурной химии). 2020. V.61. N6. P.906-913. DOI: 10.1134/s0022476620060104 WOS Scopus

Романенко Г.В. , Фокин С.В. , Толстиков С.Е. , Летягин Г.А. , Богомяков А.С. , Овчаренко В.И.
Спин-меченый линкер для дизайна координационных полимеров
Journal of Structural Chemistry (Журнал структурной химии). 2020. Т.61. №6. С.959-965. DOI: 10.26902/JSC_id57710

Опубликована online:

8 авг. 2020 г.

Web of science:	WOS:000558500700010
Scopus:	2-s2.0-85089219500

БД	Цитирований
Scopus	3
Web of science	2