Abstract: The synthesis of a novel nitronylnitroxyl radical 2-(2,5-di(pyridin-4-yl)phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-3-oxide-1-oxyl (L) and the first Mn(II) complex with it [Mn(NO3)2(L)(H2O)× ×(i-PrOH)] is elaborated and performed. It is found that the complex is formed by polymeric chains in which (NO3)2(H2O)(i-PrOH) fragmentы are linked by L coordinated by N atoms of pyridine rings. The chains are combined into layers by hydrogen bonds between the coordinated water molecules, i-PrOH, and nitrate anions. The layers are joined into a framework by weak C-H⋯O contacts between O atoms of the nitronylnitroxyl fragment and the pyridine C-H group.

Cite: Romanenko G.V. , Fokin S.V. , Tolstikov S.E. , Letyagin G.A. , Bogomyakov A.S. , Ovcharenko V.I.
Spin-Labeled Linker for the Design of Coordination Polymers
Journal of Structural Chemistry (Журнал структурной химии). 2020. V.61. N6. P.906-913. DOI: 10.1134/s0022476620060104 WOS Scopus

Original: Романенко Г.В. , Фокин С.В. , Толстиков С.Е. , Летягин Г.А. , Богомяков А.С. , Овчаренко В.И.
Спин-меченый линкер для дизайна координационных полимеров
Journal of Structural Chemistry (Журнал структурной химии). 2020. Т.61. №6. С.959-965. DOI: 10.26902/JSC_id57710

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Published online:

Aug 8, 2020

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Web of science:	WOS:000558500700010
Scopus:	2-s2.0-85089219500

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Scopus	3
Web of science	2

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