Magnetic Properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] Compounds and the X-Ray Photoelectron Analysis of Their Electronic Structures

Magnetic Properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] Compounds and the X-Ray Photoelectron Analysis of Their Electronic Structures Научная публикация

Журнал

Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766

Вых. Данные

Год: 2026, Том: 67, Номер: 3, Страницы: 632-643 Страниц : 12 DOI: 10.1134/s0022476626030157

Авторы

Asanov I.P. ¹ , Fedorenko A.D. ¹ , Berdyugin S.N. ¹ , Gaas V.A. ¹ , Bogomyakov A.S. ²

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Institute “International Tomography Center”, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

The magnetic properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] complexes are studied in the temperature range of 2-300 K. The presence of weakly interacting rhenium(IV) ions is revealed with an antiferromagnetic transition at low temperatures in the range of 11-13 K. Theoretical broken-symmetry DFT computations show a weak antiferromagnetic interaction between [ReCl6]2–. To determine zero-field splitting parameters and magnetic properties the CASSCF/NEVPT2 computations are performed with the experimental [ReCl6]2– geometries of the studied complexes.

Asanov I.P. , Fedorenko A.D. , Berdyugin S.N. , Gaas V.A. , Bogomyakov A.S.
Magnetic Properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] Compounds and the X-Ray Photoelectron Analysis of Their Electronic Structures
Journal of Structural Chemistry (Журнал структурной химии). 2026. V.67. N3. P.632-643. DOI: 10.1134/s0022476626030157 WOS Scopus OpenAlex

Асанов И.П. , Федоренко А.Д. , Берд.гин С.Н. , Гаас В.А. , Богомяков А.С.
Магнитные свойства соединений (NH4)2[ReCl6], [Pd(NH3)4][ReCl6] и [Pt(NH3)4][ReCl6] и исследование их электронной структуры методом рентгеновской фотоэлектронной спектроскопии
Journal of Structural Chemistry (Журнал структурной химии). 2026. Т.67. №3. 162529 . DOI: 10.26902/JSC_id162529 OpenAlex

Поступила в редакцию:	9 дек. 2025 г.
Принята к публикации:	11 дек. 2025 г.
Опубликована в печати:	10 апр. 2026 г.

≡ Web of science:	WOS:001737907400021
≡ Scopus:	2-s2.0-105035466509
≡ OpenAlex:	W7152999060