Magnetic Properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] Compounds and the X-Ray Photoelectron Analysis of Their Electronic Structures Full article
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Journal of Structural Chemistry (Журнал структурной химии)
ISSN: 0022-4766 |
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| Output data | Year: 2026, Volume: 67, Number: 3, Pages: 632-643 Pages count : 12 DOI: 10.1134/s0022476626030157 | ||||
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Abstract:
The magnetic properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] complexes are studied in the temperature range of 2-300 K. The presence of weakly interacting rhenium(IV) ions is revealed with an antiferromagnetic transition at low temperatures in the range of 11-13 K. Theoretical broken-symmetry DFT computations show a weak antiferromagnetic interaction between [ReCl6]2–. To determine zero-field splitting parameters and magnetic properties the CASSCF/NEVPT2 computations are performed with the experimental [ReCl6]2– geometries of the studied complexes.
Cite:
Asanov I.P.
, Fedorenko A.D.
, Berdyugin S.N.
, Gaas V.A.
, Bogomyakov A.S.
Magnetic Properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] Compounds and the X-Ray Photoelectron Analysis of Their Electronic Structures
Journal of Structural Chemistry (Журнал структурной химии). 2026. V.67. N3. P.632-643. DOI: 10.1134/s0022476626030157 WOS Scopus OpenAlex
Magnetic Properties of (NH4)2[ReCl6], [Pd(NH3)4][ReCl6], and [Pt(NH3)4][ReCl6] Compounds and the X-Ray Photoelectron Analysis of Their Electronic Structures
Journal of Structural Chemistry (Журнал структурной химии). 2026. V.67. N3. P.632-643. DOI: 10.1134/s0022476626030157 WOS Scopus OpenAlex
Original:
Асанов И.П.
, Федоренко А.Д.
, Берд.гин С.Н.
, Гаас В.А.
, Богомяков А.С.
Магнитные свойства соединений (NH4)2[ReCl6], [Pd(NH3)4][ReCl6] и [Pt(NH3)4][ReCl6] и исследование их электронной структуры методом рентгеновской фотоэлектронной спектроскопии
Journal of Structural Chemistry (Журнал структурной химии). 2026. Т.67. №3. 162529 . DOI: 10.26902/JSC_id162529 OpenAlex
Магнитные свойства соединений (NH4)2[ReCl6], [Pd(NH3)4][ReCl6] и [Pt(NH3)4][ReCl6] и исследование их электронной структуры методом рентгеновской фотоэлектронной спектроскопии
Journal of Structural Chemistry (Журнал структурной химии). 2026. Т.67. №3. 162529 . DOI: 10.26902/JSC_id162529 OpenAlex
Dates:
| Submitted: | Dec 9, 2025 |
| Accepted: | Dec 11, 2025 |
| Published print: | Apr 10, 2026 |
Identifiers:
| ≡ Web of science: | WOS:001737907400021 |
| ≡ Scopus: | 2-s2.0-105035466509 |
| ≡ OpenAlex: | W7152999060 |