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Cross-relaxation in nuclear polarization. A flash-CIDNP study Научная публикация

Журнал Chemical Physics Letters
ISSN: 0009-2614
Вых. Данные Год: 1990, Том: 171, Номер: 5-6, Страницы: 406-412 Страниц : 7 DOI: 10.1016/0009-2614(90)85238-8
Авторы Yurkovskaya A.V. 1 , Tsentalovich Yu.P. 1 , Sagdeev R.Z. 1
Организации
1 Institute of Chemical Kinetics and Combustion, 630090 Novosibirsk, USSR

Реферат: CIDNP with microsecond time resolution was used to study the kinetics of nuclear polarization formation during the photolysis of acetone in isopropanol over a wide temperature range. The coincidence of signs of multiplet effects of CIDNP (A/E) for cage and escape reaction products as well as the presence of net polarization (E) changing its sign with decreasing temperature have been revealed. The account of scalar electron-nuclear cross-relaxation has been shown to be necessary for the interpretation of the results obtained.
Библиографическая ссылка: Yurkovskaya A.V. , Tsentalovich Y.P. , Sagdeev R.Z.
Cross-relaxation in nuclear polarization. A flash-CIDNP study
Chemical Physics Letters. 1990. V.171. N5-6. P.406-412. DOI: 10.1016/0009-2614(90)85238-8 WOS Scopus OpenAlex
Идентификаторы БД:
≡ Web of science: WOS:A1990DV82800002
≡ Scopus: 2-s2.0-4243873819
≡ OpenAlex: W2048582766
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