Cross-relaxation in nuclear polarization. A flash-CIDNP study Full article
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Chemical Physics Letters
ISSN: 0009-2614 |
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| Output data | Year: 1990, Volume: 171, Number: 5-6, Pages: 406-412 Pages count : 7 DOI: 10.1016/0009-2614(90)85238-8 | ||
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Abstract:
CIDNP with microsecond time resolution was used to study the kinetics of nuclear polarization formation during the photolysis of acetone in isopropanol over a wide temperature range. The coincidence of signs of multiplet effects of CIDNP (A/E) for cage and escape reaction products as well as the presence of net polarization (E) changing its sign with decreasing temperature have been revealed. The account of scalar electron-nuclear cross-relaxation has been shown to be necessary for the interpretation of the results obtained.
Cite:
Yurkovskaya A.V.
, Tsentalovich Y.P.
, Sagdeev R.Z.
Cross-relaxation in nuclear polarization. A flash-CIDNP study
Chemical Physics Letters. 1990. V.171. N5-6. P.406-412. DOI: 10.1016/0009-2614(90)85238-8 WOS Scopus OpenAlex
Cross-relaxation in nuclear polarization. A flash-CIDNP study
Chemical Physics Letters. 1990. V.171. N5-6. P.406-412. DOI: 10.1016/0009-2614(90)85238-8 WOS Scopus OpenAlex
Identifiers:
| ≡ Web of science: | WOS:A1990DV82800002 |
| ≡ Scopus: | 2-s2.0-4243873819 |
| ≡ OpenAlex: | W2048582766 |